Product ID:F42-0401-100 CLC-700/800 TONER BLACK
MSDS Date:02/01/1994
FSC:6850
NIIN:01-431-9417
MSDS Number: CFRKQ

CANON IND

30-2 SHIRMOMARUKO 3 CHOME OMTA-KU
TOKYO
JA

Emergency Phone: 800-424-9300(CHEMTREC)

Info Phone: 516-328-5600

Preparer: JOSEPH PALMERI

Cage: EO160

CANON USA INC

NEW HYDE PARK, NY 11042 US

Telephone: 516-328-5000; 5600

Cage: 08YZ7

POLYESTER RESIN

CAS: 39382-25-7

Fraction By Weight: 85-95%

CARBON BLACK

CAS: 1333-86-4

RTECS: FF5800000

Fraction By Weight: 1-5%

OSHA PEL 3.5 MG/M3

ACGIH TLV: 3.5 MG/M3; 9596

LD50 LC50 Mixture:SIMILAR TONER LD50 RAT ORAL>5000MG/KG.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CHRONIC:BASED UPON AVAI DATA,HUMAN
EXPO TO TONER HAS BEEN SHOWN TO CAUSE MIN RESP TRACT IRRIT AS MAY
OCCUR W/LG AMTS OF ANY NONTOXIC DUSTS.RESULTS OF 1 ANIMAL STUDY
WHERE RATS INHAL TONER THAT WAS 10X MORE RESPIRABLE THAN
COMMERCIALLY AVAITONER WERE OBSERVED TO HAVE NO LUNG CHANGES @LOW
EXPO(MOST RELEVANT LEVEL(SUPPL)
Explanation of Carcinogenicity:PER MSDS:CARCINOGENICITY
CLASSIFICATION:IARC/ACGIH/OSHA/NTP:NONE.
Effects of Overexposure:TRANSIENT EYE IRRITATION.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INHAL:SYMPTOMATIC MOVE TO FRESH AIR.GET MED ATTN IF SYMPTOMS
PERSIST.EYE:ANY MATL THAT CONACTGS EYE SHOULD BE WASHED OUT IMMED
W/WATER.GET MED ATTN IF SYMPTOMS OCCUR.SKIN:WASH W/SOAP/WATER.GET
MED ATT N IF SYMPTOMS OCCUR.INGEST:DRINK 1-2GLASSES OF WATER.SEEK
MED ATTN.

Flash Point:NA
Autoignition Temp:Autoignition Temp Text:NP
Lower Limits:NA
Upper Limits:NA
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE (CO2), DRY CHEMICAL.
Fire Fighting Procedures:NONE
Unusual Fire/Explosion Hazard:POWDERED MATLS MAY FORM EXPLOSIVE
DUST-AIR MIXTURES. NON-FLAMM SOLID(ACCORDING TO TEST METHODS OF
16CFR1500.44).

Spill Release Procedures:SWEEP MATERIAL ONTO PAPER AND PLACE IN FIBER
CARTON.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:AVOID BREATH DUST.USE W/ADEQUATE
VENTILATION.KEEP FRM CONTACT W/OXIDIZINGS MATLS.MINIMIZE DUST
GENERATION & ACCUMULATION.
Other Precautions:REFER TO PAMPHLET #654:"PREVENTION OF FIRE/DUST
EXPLOSIONS IN CHEMICAL,DYE,PHARMACEUTRICAL,PLASTICS INDUSTRIES."USE
ADEQUATE VENTILATION.KEEP CONTAINER CLOSED. EMPTY RECEPTACLE MAY BE
RECYCLED.MATL HA SNT BEEN TEST FOR ENVIRO EFFECTS.

Respiratory Protection:NONE SHOULD BE NEEDED.
Ventilation:GOOD VENTI(TYPICALLY 4-6ROOM VOL/HR)SHOULD BE USED.VENTI
RATES SHOULD BE MATCHED TO CONDITIONS.
Protective Gloves:IMPERVIOUS GLOVES
Eye Protection:GOOD INDUSTRIAL HYGIENE PRACTICE
Other Protective Equipment:FACILITIES:WASHING FACILITIES.
Work Hygienic Practices:WASH THOROUGHLY AFTER HNDLING.
Supplemental Safety and Health
HEALTH:TO POTENTIAL HUMAN EXPO)>@IGHER LEVELS SLIGHT DEGREE OF LUNG
FIBROSIS WAS OBSERVED DUE TO EXCESSIVE AMTS OF DUST RETAINED IN
LUNGS FOR PROLONGED INTERVAL.INHAL/SKIN:EXPECTED TO BE LOW HAZ FOR
R ECOMMENDED HNDLG.EYE:NO SPEC HAZ KNOWN.MAY CAUSE TRANS
IRRIT.INGEST:EXPECTED TO BE LOW INGEST HAZ.

HCC:N1
Melt/Freeze Pt:M.P/F.P Text:212F,100C
Decomp Temp:Decomp Text:NP
Vapor Pres:NA
Vapor Density:NA
Spec Gravity:1.0-1.2
pH:NA
Viscosity:NP
Evaporation Rate & Reference:NA
Solubility in Water:NEGLIGIBLE
Appearance and Odor:SOLID POWDER, BLACK COLOR, SLIGHT PLASTIC ODOR
Percent Volatiles by Volume:NP
Corrosion Rate:NP

Stability Indicator/Materials to Avoid:YES
STGRONG OXIDIZING AGENTS
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:CARBON DIOXIDE,CARBON MONOXIDE.COMBUST
WILL PRODUCE CARBON DIOXIDE & POSSIBLY TOXIC CHEMS SUCH CO OR
OXIDES OF NITROGEN.

Waste Disposal Methods:SPILL SITUATION MATL MAY BE VISUALLY
UNPLEASANT;HOWEVER NOT EXPECTED TO CAUSE ANY ADVERSE ENVIRO
EFFECTS.INCINE/LANDFILL.CAN BE INCINERATED WHEN ICW/LOC
REGS.DISCHARG/TREAT/DISPO SUBJ TO NAT/STATE/LOC LAWS.CHEM SUBJ TO
REPORT REQMTS SARA SEC313.

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This information is formulated for use by elements of the Department
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expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.